Issue 87, 2022

Optical sensing of aqueous nitrate anion by a platinum(ii) triimine salt based solid state material

Abstract

Selective and quantitative measurement of aqueous nitrate (NO3) anion is achieved using solid [Pt(Cl-4-tpy)Cl]ClO4 salt (Cl-4-tpy = 4-chloro-2,2′:6′2′′-terpyridine), and as the salt supported on controlled porous glass. This detection method relies on the color change of the Pt(II) complex from yellow to red and intense luminescence response upon ClO4 exchange with NO3 due to concomitant enhancement of Pt⋯Pt interactions. The spectroscopic response is highly selective for NO3 over a large range of halides and oxoanions.

Graphical abstract: Optical sensing of aqueous nitrate anion by a platinum(ii) triimine salt based solid state material

Supplementary files

Article information

Article type
Communication
Submitted
26 Aug. 2022
Accepted
22 Sept. 2022
First published
26 Sept. 2022

Chem. Commun., 2022,58, 12160-12163

Author version available

Optical sensing of aqueous nitrate anion by a platinum(II) triimine salt based solid state material

A. E. Norton, M. Karimi Abdolmaleki, L. Andriot, C. Cashen, J. A. Krause, W. B. Connick and S. Chatterjee, Chem. Commun., 2022, 58, 12160 DOI: 10.1039/D2CC04732B

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