Issue 69, 2022

3-Ethyl-6-vinyltetrahydro-2H-pyran-2-one (EVP): a versatile CO2-derived lactone platform for polymer synthesis

Abstract

3-Ethyl-6-vinyltetrahydro-2H-pyran-2-one (EVP) is a CO2-derived lactone synthesized via Pd-catalyzed telomerization of butadiene. As EVP is 28.9% by weight CO2, it has received significant recent attention as an intermediary for the synthesis of high CO2-content polymers. This article provides an overview of strategies for the polymerization of EVP to a wide variety of polymer structures, ranging from radical polymerizations to ring-opening polymerizations, that each take unique advantage of the highly functionalized lactone.

Graphical abstract: 3-Ethyl-6-vinyltetrahydro-2H-pyran-2-one (EVP): a versatile CO2-derived lactone platform for polymer synthesis

Article information

Article type
Feature Article
Submitted
23 Jūn. 2022
Accepted
10 Aug. 2022
First published
10 Aug. 2022

Chem. Commun., 2022,58, 9586-9593

Author version available

3-Ethyl-6-vinyltetrahydro-2H-pyran-2-one (EVP): a versatile CO2-derived lactone platform for polymer synthesis

R. M. Rapagnani and I. A. Tonks, Chem. Commun., 2022, 58, 9586 DOI: 10.1039/D2CC03516B

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