Issue 25, 2022
From the journal:

Chemical Communications

Exchange of coordinated carboxylates with azolates as a route to obtain a microporous zinc–azolate framework†

Kira M. Fahy, ORCID logo a   Mohammad Rasel Mian,a   Megan C. Wasson, ORCID logo a   Florencia A. Son, ORCID logo a   Timur Islamoglu ORCID logo *a  and  Omar K. Farha ORCID logo *ab  

* Corresponding authors

a International Institute for Nanotechnology and Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA
E-mail: timur.islamoglu@northwestern.edu, o-farha@northwestern.edu

b Department of Chemical & Biological Engineering, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA

Abstract

Metal–organic frameworks (MOFs) containing open metal sites are advantageous for wide applications. Here, carboxylate linkers are replaced with triazolate coordination in pre-formed Zn-MOF-74 via solvent-assisted linker exchange (SALE) to prepare the novel NU-250, within the known hexagonal channel-based MAF-X25 series that has not previously been synthesized de novo.

Graphical abstract: Exchange of coordinated carboxylates with azolates as a route to obtain a microporous zinc–azolate framework

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Article information

DOI
https://doi.org/10.1039/D2CC00925K
Article type
Communication
Submitted
15 Febr. 2022
Accepted
25 Febr. 2022
First published
07 Marts 2022

Chem. Commun., 2022,58, 4028-4031

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Exchange of coordinated carboxylates with azolates as a route to obtain a microporous zinc–azolate framework

K. M. Fahy, M. R. Mian, M. C. Wasson, F. A. Son, T. Islamoglu and O. K. Farha, Chem. Commun., 2022, 58, 4028 DOI: 10.1039/D2CC00925K

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