Issue 19, 2022

AuB8: an Au–borozene complex

Abstract

Photoelectron spectroscopy and quantum chemistry studies are used to investigate the structure and bonding of AuB8. Global minimum sturctural searches show that AuB8 possesses a chair-like structure, which can be viewed as Au+ bonded to the edge of the doubly-aromatic B82− borozene, Au+2-B82−]. Chemical bonding analyses reveal that the AuB8 is a novel borozene complex with unique Au–borozene bonding.

Graphical abstract: AuB8−: an Au–borozene complex

Supplementary files

Article information

Article type
Communication
Submitted
06 Janv. 2022
Accepted
09 Febr. 2022
First published
09 Febr. 2022

Chem. Commun., 2022,58, 3134-3137

Author version available

AuB8: an Au–borozene complex

W. Chen, Y. Zhang, W. Li, H. W. Choi, J. Li and L. Wang, Chem. Commun., 2022, 58, 3134 DOI: 10.1039/D1CC07303F

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