Issue 74, 2021

Reactivity of an N-heterocyclic silylene with a 1,1′-ferrocenediyl backbone towards carbonyl compounds, including carbon suboxide

Abstract

Reactions of a silylene with a ketene and with carbon suboxide are reported, respectively leading to the first silaallene oxide and to a silylketene, whose reaction with water affords the first structurally characterised stable methyleneketene and constitutes a unique type of single-crystal-to-single-crystal transformation of a molecular solid by a stoichiometric gas–solid chemical reaction.

Graphical abstract: Reactivity of an N-heterocyclic silylene with a 1,1′-ferrocenediyl backbone towards carbonyl compounds, including carbon suboxide

Supplementary files

Article information

Article type
Communication
Submitted
21 Jūl. 2021
Accepted
19 Aug. 2021
First published
19 Aug. 2021

Chem. Commun., 2021,57, 9378-9381

Reactivity of an N-heterocyclic silylene with a 1,1′-ferrocenediyl backbone towards carbonyl compounds, including carbon suboxide

N. Weyer, M. Heinz, C. Bruhn, M. C. Holthausen and U. Siemeling, Chem. Commun., 2021, 57, 9378 DOI: 10.1039/D1CC03947D

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