Issue 79, 2021

Organic guest molecule induced ultrafast breathing of an epitaxially grown metal–organic framework on a self-assembled monolayer

Abstract

We report epitaxially grown new two-dimensional metal–organic framework (MOF) thin films on a self-assembled monolayer (SAM). We fabricated these epitaxial thin-films using stepwise layer-by-layer seeding followed by solvothermal treatment. The MOF thin films exhibit ultrafast structural flexibility (through breathing) compared to their bulk samples upon uptake of organic guest molecules.

Graphical abstract: Organic guest molecule induced ultrafast breathing of an epitaxially grown metal–organic framework on a self-assembled monolayer

Associated articles

Supplementary files

Article information

Article type
Communication
Submitted
10 Jūl. 2021
Accepted
01 Sept. 2021
First published
01 Sept. 2021

Chem. Commun., 2021,57, 10158-10161

Organic guest molecule induced ultrafast breathing of an epitaxially grown metal–organic framework on a self-assembled monolayer

P. C. Rao, P. Mani, Y. Son, J. Kim and M. Yoon, Chem. Commun., 2021, 57, 10158 DOI: 10.1039/D1CC03721H

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