Issue 65, 2021

Pd-catalyzed selective tetrafunctionalization of diiodo-o-carboranes

Abstract

A palladium-catalyzed highly selective tetrafunctionalization of 3,6-I2-o-carborane and 4,7-I2-o-carborane has been developed, leading to the preparation of 3,6-dialkenyl-4,11-R2-o-carboranes and 4,7-dialkenyl-5,11-R2-o-carboranes (R = alkyl, allyl and aryl) in moderate to excellent yields. This represents a new strategy for selective synthesis of polyfunctionalized o-carborane derivatives via a one-pot process.

Graphical abstract: Pd-catalyzed selective tetrafunctionalization of diiodo-o-carboranes

Supplementary files

Article information

Article type
Communication
Submitted
28 Jūn. 2021
Accepted
19 Jūl. 2021
First published
20 Jūl. 2021

Chem. Commun., 2021,57, 8071-8074

Pd-catalyzed selective tetrafunctionalization of diiodo-o-carboranes

Y. Ge, Z. Qiu and Z. Xie, Chem. Commun., 2021, 57, 8071 DOI: 10.1039/D1CC03449A

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