Issue 79, 2021

Thiophene-fused boracycles as photoactive analogues of diboraanthracenes

Abstract

The construction of thiophene-fused analogues of diboraanthracenes with different aryl substituents through boron-mercury exchange followed by the nucleophilic replacement of the chlorines of dichlorodiboradithiophene 2 with Grignard reagents is reported. These diboradithiophenes exhibited unusual photophysical and electrochemical properties. They all undergo photoisomerisation, which can be traced using photophysical and 1H NMR spectroscopy studies.

Graphical abstract: Thiophene-fused boracycles as photoactive analogues of diboraanthracenes

Supplementary files

Article information

Article type
Communication
Submitted
22 Jūn. 2021
Accepted
06 Sept. 2021
First published
06 Sept. 2021

Chem. Commun., 2021,57, 10170-10173

Thiophene-fused boracycles as photoactive analogues of diboraanthracenes

S. Sa, A. C. Murali, P. Nayak and K. Venkatasubbaiah, Chem. Commun., 2021, 57, 10170 DOI: 10.1039/D1CC03323A

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