Issue 11, 2019

Redox chemistry of an anionic dithiolene radical

Abstract

The redox chemistry of the first stable anionic dithiolene radical was investigated by both reactivity and cyclic voltammetry studies. While one-electron reduction of by Cp2Co or KC8 affords the corresponding dithiolate dimers 2 and 3, respectively, one-electron oxidation of by Ph3C+BF4 (or O2) conveniently gives 4, the neutral dithiolene dimer.

Graphical abstract: Redox chemistry of an anionic dithiolene radical

Supplementary files

Article information

Article type
Communication
Submitted
18 Dec. 2018
Accepted
07 Febr. 2019
First published
07 Febr. 2019

Dalton Trans., 2019,48, 3543-3546

Author version available

Redox chemistry of an anionic dithiolene radical

Y. Wang, Y. Xie, P. Wei, H. F. Schaefer and G. H. Robinson, Dalton Trans., 2019, 48, 3543 DOI: 10.1039/C8DT04989K

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