Issue 92, 2019

A single-crystal-to-single-crystal transformation affording photochromic 3D MORF crystals

Abstract

Metal–organic framework (MOF) type crystals in which rigid, viologen-based pillars are surrounded by cucurbit[7]uril (CB[7]) macrocycles are described. These metal–organic rotaxane frameworks (MORF) are obtained by desolvation of a crystal precursor featuring a network already near-optimal toward 3D metal–ligand reticulation and show reversible photochromism.

Graphical abstract: A single-crystal-to-single-crystal transformation affording photochromic 3D MORF crystals

Supplementary files

Article information

Article type
Communication
Submitted
11 Sept. 2019
Accepted
22 Okt. 2019
First published
23 Okt. 2019

Chem. Commun., 2019,55, 13824-13827

A single-crystal-to-single-crystal transformation affording photochromic 3D MORF crystals

X. Yang, M. Giorgi, H. Karoui, D. Gigmes, V. Hornebecq, O. Ouari, A. Kermagoret and D. Bardelang, Chem. Commun., 2019, 55, 13824 DOI: 10.1039/C9CC07121K

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