Issue 44, 2018

Solvent-free synthesis of a porous thiophene polymer by mechanochemical oxidative polymerization

Abstract

This study elucidates a mechanochemical approach to synthesize a microporous thiophene polymer via oxidative polymerization. Utilizing a design of experiments approach we optimized the reaction conditions leading to complete conversion and a polymer with a surface area of up to 1850 m2 g−1 – almost twice as high as the material prepared by solution-based polymerization. Thus, our approach presents a solvent free, quick and scalable alternative for the production of porous polymers.

Graphical abstract: Solvent-free synthesis of a porous thiophene polymer by mechanochemical oxidative polymerization

Supplementary files

Article information

Article type
Communication
Submitted
21 Apr. 2018
Accepted
12 Jūn. 2018
First published
12 Jūn. 2018

J. Mater. Chem. A, 2018,6, 21901-21905

Solvent-free synthesis of a porous thiophene polymer by mechanochemical oxidative polymerization

S. Grätz, M. Oltermann, E. Troschke, S. Paasch, S. Krause, E. Brunner and L. Borchardt, J. Mater. Chem. A, 2018, 6, 21901 DOI: 10.1039/C8TA03684E

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