Issue 42, 2018

Dynamic behaviour in nonporous hybrid metal–organic materials via mechanochemical and gas–solid reactions

Abstract

Nonporous hybrid metal–organic materials self-assembled by a ditopic organic ligand and copper(II) have shown a dynamic behavior by releasing and trapping HCl. The solid-state process involves major structural reorganizations comprising cleavage and formation of coordination and covalent chemical bonds by mechanochemical reactions, heating reactions or chemisorption. Single crystal X-ray diffraction, powder X-ray diffraction and TGA in combination with DFT specific for solid-state systems have been used to study the solid-state reactivity.

Graphical abstract: Dynamic behaviour in nonporous hybrid metal–organic materials via mechanochemical and gas–solid reactions

Supplementary files

Article information

Article type
Paper
Submitted
02 Aug. 2018
Accepted
28 Sept. 2018
First published
28 Sept. 2018

CrystEngComm, 2018,20, 6721-6726

Dynamic behaviour in nonporous hybrid metal–organic materials via mechanochemical and gas–solid reactions

F. Guo, H. Wang, A. Famulari, H. Lu and J. Martí-Rujas, CrystEngComm, 2018, 20, 6721 DOI: 10.1039/C8CE01287C

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