Issue 85, 2018

Organosoluble tetravalent actinide di- and trifluorides

Abstract

Soluble molecular actinide(IV) fluorides can be prepared in high yield via redox or metathesis reactions of silver fluorides with actinide compounds containing ancillary iodide or fluorinated thiolate ligands. Two compounds, (py)4UF2I2·2py and (py)7Th2F5(SC6F5)3·2py were isolated and characterized by conventional methods, powder and low temperature single crystal X-ray diffraction.

Graphical abstract: Organosoluble tetravalent actinide di- and trifluorides

Supplementary files

Article information

Article type
Communication
Submitted
09 Jūl. 2018
Accepted
02 Okt. 2018
First published
10 Okt. 2018

Chem. Commun., 2018,54, 12018-12020

Organosoluble tetravalent actinide di- and trifluorides

G. Gotthelf, M. A. Stuber, A. Y. Kornienko, T. J. Emge and J. G. Brennan, Chem. Commun., 2018, 54, 12018 DOI: 10.1039/C8CC05501G

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