Issue 96, 2018

Actinide-transition metal bonding in heterobimetallic uranium– and thorium–molybdenum paddlewheel complexes

Abstract

We report the preparation of four heterobimetallic uranium– and thorium–molybdenum paddlewheel complexes. The characterisation data suggest the presence of Mo → An σ-interactions in all cases. These complexes represent unprecedented actinide-group 6 metal–metal bonds, where before heterobimetallic uranium–metal bonds were restricted to group 7–11 metals.

Graphical abstract: Actinide-transition metal bonding in heterobimetallic uranium– and thorium–molybdenum paddlewheel complexes

Supplementary files

Article information

Article type
Communication
Submitted
30 Jūn. 2018
Accepted
07 Nov. 2018
First published
09 Nov. 2018

Chem. Commun., 2018,54, 13515-13518

Actinide-transition metal bonding in heterobimetallic uranium– and thorium–molybdenum paddlewheel complexes

A. J. Ayres, M. Zegke, J. P. A. Ostrowski, F. Tuna, E. J. L. McInnes, A. J. Wooles and S. T. Liddle, Chem. Commun., 2018, 54, 13515 DOI: 10.1039/C8CC05268A

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