Issue 75, 2018

Revisiting complexation thermodynamics of transplutonium elements up to einsteinium

Abstract

Literature casts einsteinium as a departure from earlier transplutonium actinides, with a decrease in stability constants with aminopolycarboxylate ligands. This report studies transplutonium chemistry – including Am, Bk, Cf, and Es – with aminopolycarboxylate ligands. Es complexation follows similar thermodynamic and structural trends established by the earlier actinides, consistent with first-principle calculations.

Graphical abstract: Revisiting complexation thermodynamics of transplutonium elements up to einsteinium

Supplementary files

Article information

Article type
Communication
Submitted
02 Jūl. 2018
Accepted
28 Aug. 2018
First published
29 Aug. 2018

Chem. Commun., 2018,54, 10578-10581

Author version available

Revisiting complexation thermodynamics of transplutonium elements up to einsteinium

M. P. Kelley, N. P. Bessen, J. Su, M. Urban, S. I. Sinkov, G. J. Lumetta, E. R. Batista, P. Yang and J. C. Shafer, Chem. Commun., 2018, 54, 10578 DOI: 10.1039/C8CC05230A

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