Issue 43, 2017

Photo-induced copper-catalyzed C–H chalcogenation of azoles at room temperature

Abstract

Inexpensive copper catalysts enabled direct C–H chalcogenations at ambient temperature by means of photo-induced catalysis. The expedient copper catalysis set the stage for C–S and C–Se bond formation from readily accessible non-volatile elemental chalcogens. The photo-assisted copper catalysis manifold proved suitable for a wide range of substrates with good functional group tolerance and exhibited high catalytic efficacy even at a reaction temperature of 25 °C.

Graphical abstract: Photo-induced copper-catalyzed C–H chalcogenation of azoles at room temperature

Supplementary files

Article information

Article type
Communication
Submitted
22 Apr. 2017
Accepted
08 Maijs 2017
First published
10 Maijs 2017

Chem. Commun., 2017,53, 5906-5909

Photo-induced copper-catalyzed C–H chalcogenation of azoles at room temperature

P. Gandeepan, J. Mo and L. Ackermann, Chem. Commun., 2017, 53, 5906 DOI: 10.1039/C7CC03107F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements