Issue 50, 2017

Metal-free radical trifluoromethylation of β-nitroalkenes through visible-light photoredox catalysis

Abstract

A catalytic method for functional group interconversion is immensely important in modern sciences. Here, we report an efficient catalytic conversion of nitroalkenes to highly stereoselective 1-trifluoromethylalkenes at room temperature. This unprecedented metal-free photocatalytic strategy is simple and operates under visible-light irradiation using the commercially available CF3 source.

Graphical abstract: Metal-free radical trifluoromethylation of β-nitroalkenes through visible-light photoredox catalysis

Supplementary files

Article information

Article type
Communication
Submitted
04 Apr. 2017
Accepted
31 Maijs 2017
First published
31 Maijs 2017

Chem. Commun., 2017,53, 6760-6763

Metal-free radical trifluoromethylation of β-nitroalkenes through visible-light photoredox catalysis

S. P. Midya, J. Rana, T. Abraham, B. Aswin and E. Balaraman, Chem. Commun., 2017, 53, 6760 DOI: 10.1039/C7CC02589K

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