Issue 19, 2015

Sodium and rhodium complexes of a spirocyclic Te5 dianion supported by P2N2 rings

Abstract

Reactions of the dianion [Te(tBuN)P(μ-NtBu)2P(NtBu)Te]2− with I2 or [Cp*RhCl2]2 unexpectedly produced complexes of the novel spirocyclic Te5 dianion [{tBuN(Te)P(μ-NtBu)2P(Te)NtBu}2μ-Te]2−, which is N,N′-coordinated to two Na+ ions in the disodium derivative and adopts a Te,Te′,Te′′-bonding mode in the Cp*Rh complex.

Graphical abstract: Sodium and rhodium complexes of a spirocyclic Te5 dianion supported by P2N2 rings

Supplementary files

Article information

Article type
Communication
Submitted
21 Okt. 2014
Accepted
03 Dec. 2014
First published
06 Janv. 2015

Dalton Trans., 2015,44, 8781-8783

Sodium and rhodium complexes of a spirocyclic Te5 dianion supported by P2N2 rings

A. Nordheider, K. S. Athukorala Arachchige, A. M. Z. Slawin, J. D. Woollins and T. Chivers, Dalton Trans., 2015, 44, 8781 DOI: 10.1039/C4DT03257H

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