Issue 39, 2013
From the journal:

Chemical Communications

Controlled folding of a novel electroactive polyolefin via multiple sequential orthogonal intra-chain interactions†‡

Danming Chao,ab   Xiaoteng Jia,b   Bryan Tuten,a   Ce Wangb  and  Erik B. Berda*a  

* Corresponding authors

a Department of Chemistry and Materials Science Program, University of New Hampshire, Durham, NH 03824, USA
E-mail: Erik.Berda@unh.edu
Fax: +1 603-862-4278
Tel: +1 603-862-1762

b Alan G. MacDiarmid Institute, College of Chemistry, Jilin University, Changchun, P. R. China

Abstract

We report here the synthesis of a novel electroactive polyolefin and demonstrate through a combination of SEC-MALS and DLS how this type of functional polymer can be folded in a controlled fashion from an expanded coil to a tightly wound globule using sequentially activated noncovalent and covalent intra-chain interactions.

Graphical abstract: Controlled folding of a novel electroactive polyolefin via multiple sequential orthogonal intra-chain interactions

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Article information

DOI
https://doi.org/10.1039/C2CC37157J
Article type
Communication
Submitted
01 Okt. 2012
Accepted
03 Dec. 2012
First published
03 Dec. 2012

Chem. Commun., 2013,49, 4178-4180

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Controlled folding of a novel electroactive polyolefin via multiple sequential orthogonal intra-chain interactions

D. Chao, X. Jia, B. Tuten, C. Wang and E. B. Berda, Chem. Commun., 2013, 49, 4178 DOI: 10.1039/C2CC37157J

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