Issue 14, 2009

Aromatic trifluoromethylation catalytic in copper

Abstract

Cu(I)-diamine complexes were found to catalyse the trifluoromethylation of aryl iodides. In the presence of a small amount of CuX (X = Cl, Br, I) and 1,10-phenanthroline (phen), the cross-coupling reactions of iodoarenes with trifluoromethylsilanes proceeded smoothly to afford trifluoromethylated aromatics in good yields.

Graphical abstract: Aromatic trifluoromethylation catalytic in copper

Supplementary files

Article information

Article type
Communication
Submitted
24 Dec. 2008
Accepted
30 Janv. 2009
First published
23 Febr. 2009

Chem. Commun., 2009, 1909-1911

Aromatic trifluoromethylation catalytic in copper

M. Oishi, H. Kondo and H. Amii, Chem. Commun., 2009, 1909 DOI: 10.1039/B823249K

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