Issue 16, 2007

Alkali-metal bis(aryl)formamidinates: a study of coordinative versatility

Abstract

The development of alkali-metal amidinate reagents, in particular formamidinates, has proceeded hand-in-hand with fundamental advances in transition-metal bonding, e.g. metal–metal bonding, and the progressive departure from cyclopentadienyl support ligands in early transition-metal catalysis. This highly personalised account highlights the coordinative versatility of one alkali-metal amidinate subclass; the bis(aryl)formamidinates. These compounds have proven invaluable during transition-metal studies but were considered unworthy of investigation in their own right prior to our work.

Graphical abstract: Alkali-metal bis(aryl)formamidinates: a study of coordinative versatility

Article information

Article type
Feature Article
Submitted
26 Sept. 2006
Accepted
22 Nov. 2006
First published
05 Janv. 2007

Chem. Commun., 2007, 1579-1590

Alkali-metal bis(aryl)formamidinates: a study of coordinative versatility

P. C. Junk and M. L. Cole, Chem. Commun., 2007, 1579 DOI: 10.1039/B613984A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements