Novel carbamothioate-mediated sulfonyl fluoride synthesis enables chalcone functionalization without Michael addition side reactions.
Several fluorinated cannabinol compounds (3a–g) were synthesised via an electrophilic fluorination process.
The catalytic aminofluorination of styrenes using novel N–F reagents with deprotectable substituents, and the selective deprotection of the resulting products are disclosed.
This perspective highlights the potential of gold(II) complexes in catalysis, shedding light on the pivotal roles played by mononuclear and dinuclear gold(II) complexes, whether as isolated entities or proposed intermediates, in catalytic reactions.
In this review, we present six methodologies for the synthesis of cyclooctyne derivatives, which are important reactants in bioorthogonal chemistry. Key aspects like the broad applicability and feasibility of these synthetic pathways are discussed.