Issue 54, 2022

A viologen-functionalized metal–organic framework for efficient CO2 photoreduction reaction

Abstract

Here, a viologen-functionalized metal–organic framework (MOF), MIL-125-RV2+, was obtained by modification of MIL-125-NH2 with viologen molecules. MIL-125-RV2+, the first viologen-based MOF for photocatalytic CO2RR, exhibited excellent photocatalytic activity and high selectivity for HCOO. The strategy of using photo-responsive color-changing organics to functionalize the MOF is significant for achieving efficient CO2RR.

Graphical abstract: A viologen-functionalized metal–organic framework for efficient CO2 photoreduction reaction

Supplementary files

Article information

Article type
Communication
Submitted
10 geg. 2022
Accepted
07 birž. 2022
First published
07 birž. 2022

Chem. Commun., 2022,58, 7507-7510

A viologen-functionalized metal–organic framework for efficient CO2 photoreduction reaction

T. Wang, L. Zhang, J. Liu, X. Li, L. Yuan, S. Li and Y. Lan, Chem. Commun., 2022, 58, 7507 DOI: 10.1039/D2CC02650C

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