Issue 15, 2019

Modulation of catalyst enantioselectivity through reversible assembly of supramolecular helices

Abstract

A multi-configurable catalyst, for which the degree of enantioinduction in successive reactions is varied between 6% ee and 52% ee, is achieved by supporting copper centres at the periphery of supramolecular helices. Precise characterization of the co-assemblies corroborates the relation between helix length and catalyst selectivity.

Graphical abstract: Modulation of catalyst enantioselectivity through reversible assembly of supramolecular helices

Supplementary files

Article information

Article type
Communication
Submitted
11 gruod. 2018
Accepted
18 saus. 2019
First published
18 saus. 2019

Chem. Commun., 2019,55, 2162-2165

Modulation of catalyst enantioselectivity through reversible assembly of supramolecular helices

Y. Li, X. Caumes, M. Raynal and L. Bouteiller, Chem. Commun., 2019, 55, 2162 DOI: 10.1039/C8CC09819K

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