Issue 91, 2018

A family of molecular nickel hydrogen evolution catalysts providing tunable overpotentials using ligand-centered proton-coupled electron transfer paths

Abstract

Two new nickel dithiolate derivatives have been examined for their electrocatalytic activity for the hydrogen evolution reaction (HER) in attempts to clarify whether the overpotential for the HER can be tuned upon varying the ligand-centered reduction potential that triggers the HER by the catalysts. We demonstrate the validity of this approach to achieve desirable tunability in the overpotential for the HER.

Graphical abstract: A family of molecular nickel hydrogen evolution catalysts providing tunable overpotentials using ligand-centered proton-coupled electron transfer paths

Supplementary files

Article information

Article type
Communication
Submitted
14 rugs. 2018
Accepted
19 spal. 2018
First published
20 spal. 2018

Chem. Commun., 2018,54, 12820-12823

A family of molecular nickel hydrogen evolution catalysts providing tunable overpotentials using ligand-centered proton-coupled electron transfer paths

Y. Aimoto, K. Koshiba, K. Yamauchi and K. Sakai, Chem. Commun., 2018, 54, 12820 DOI: 10.1039/C8CC07467D

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