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Novel Brønsted acid–base ionic liquids, derived from a simple combination of a wide variety of organic amines with bis(trifluoromethanesulfonyl) amide are electroactive for H2 oxidation and O2 reduction at a Pt electrode under non-humidifying conditions, which shows the prospect of the use of protic ionic liquids as new materials for anhydrous proton conductors at elevated temperatures.

Graphical abstract: Brønsted acid–base ionic liquids and their use as new materials for anhydrous proton conductors

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