Issue 8, 1994

Synthetic approaches to [n](3,5)-troponophanes. Novel rearrangements of 10, 10-dichloro-1,2,6,7,8,9-hexahydro-4a,9a-methano-5H-benzocyyclohepten-2-one

Abstract

On standing the title compound 1c gives an enone isomer 4 and the heptacyclic compound 5; the formation of both of these products has been rationalised in terms of the intermediacy of the bridged tropylium ion 8 and 13C-labelling studies support this proposal.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 1015-1017

Synthetic approaches to [n](3,5)-troponophanes. Novel rearrangements of 10, 10-dichloro-1,2,6,7,8,9-hexahydro-4a,9a-methano-5H-benzocyyclohepten-2-one

M. G. Banwell, R. W. Gable, J. H. Ryan and M. F. Mackay, J. Chem. Soc., Chem. Commun., 1994, 1015 DOI: 10.1039/C39940001015

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements