Proton-promoted disproportionation of iron(v)-imido TAML to iron(v)-imido TAML cation radical and iron(iv) TAML

Abstract

The present study reports the first example of a proton-promoted disproportionation reaction of a non-heme iron(V)-imido TAML (1) complex to give an iron(V)-imido TAML cation radical (2) and an iron(IV) TAML (3) upon addition of acids. Detailed mechanistic investigations revealed that two molecules of 1 react with one proton to yield 2 and [Fe^IV(NHTs)(TAML)]⁻ (4), followed by the reaction of 4 with another proton to afford 3 and NH₂Ts.