Cofactor bonding, hydrogen peroxide activation, and bromide oxidation by marine bromoperoxidases are explained in a unified model, based on quantitative approaches for scaling peroxide electrophilicity and orthovanadate hydrogen bonding.
The scope of biomimicking vanadium bromoperoxidase in producing bromonium ions and its further utilisation in conducting oxidative bromination or cleavage of various organic molecules has been described in this review.
A highly precise colorimetric detection method for MTX was developed based on the Bi2WO6 halogen peroxidase (HPO)-like nanozyme.
The picture illustrates most of the haloperoxidases that have been reported.
In this article, we review the key processes contributing to the chemical diversity of terpenes in red algae. We present knowledge gaps and perspectives for heterologous biosynthesis.