Issue 7, 2023

Single liquid aerosol nano-impact electrochemistry: accessing the droplet|air interface

Abstract

Over the past decade, many groups have shown that chemistry changes drastically in confined volumes compared to large volumes. As a robust analytical chemistry tool, electrochemistry has augmented the discussion because of its ability to study reactivity of single atoms, molecules, and nanoparticles, one at a time. Unfortunately, this field of science, known as nano-impact electrochemistry, has been limited to studying sub-femtoliter liquid droplets suspended in oil because measurements require at least two electrodes. Here, we develop a miniaturizable platform for the nano-impact electrochemical study of single liquid aerosol droplets. We achieve detection by the miniaturization of laser-pulled, dual-barrel ultramicroelectrodes, where two Pt ultramicroelectrodes are separated by a distance of a few micrometers. When aerosols loaded with a 1 : 1 solution of 300 mM hexacyanoferrate(II/III) are nebulized, discrete transients, indicative of single aerosol droplet collisions with the nanoprobe, can be observed in the amperometric it trace. Using finite element modeling, we demonstrate the amperometric signal depends on the aerosol droplet geometry at the nanoprobe. Our results push the limit of what is measurable by taking electroanalysis to the single aerosol level. These experiments also allow access to the study of chemical reactions at the droplet|air interface.

Graphical abstract: Single liquid aerosol nano-impact electrochemistry: accessing the droplet|air interface

Supplementary files

Article information

Article type
Communication
Submitted
15 Mar 2023
Accepted
13 Apu 2023
First published
13 Apu 2023

Environ. Sci.: Nano, 2023,10, 1744-1748

Author version available

Single liquid aerosol nano-impact electrochemistry: accessing the droplet|air interface

P. J. Kauffmann and J. E. Dick, Environ. Sci.: Nano, 2023, 10, 1744 DOI: 10.1039/D3EN00156C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements