Pyridine-2-thiolate bridged tin–palladium complexes with Sn(PdN2Cl2), Sn(PdN2S2), Sn(PdN2C2) and Sn(Pd2N4) skeletons

Erik Wächtler; Robert Gericke; Lyuben Zhechkov; Thomas Heine; Thorsten Langer; Birgit Gerke; Rainer Pöttgen; Jörg Wagler

doi:10.1039/C3CC47912A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Pyridine-2-thiolate bridged tin–palladium complexes with Sn(PdN₂Cl₂), Sn(PdN₂S₂), Sn(PdN₂C₂) and Sn(Pd₂N₄) skeletons†‡

Erik Wächtler,^a Robert Gericke,^a Lyuben Zhechkov,^b Thomas Heine,^b Thorsten Langer,^c Birgit Gerke,^c Rainer Pöttgen^c and Jörg Wagler*^a

Author affiliations

* Corresponding authors

^a Institut für Anorganische Chemie, TU Bergakademie Freiberg, D-09596 Freiberg, Germany
E-mail: joerg.wagler@chemie.tu-freiberg.de
Fax: +49 3731 39 4058

^b School of Engineering and Science, Theoretical Physics – Theoretical Materials Science, Jacobs University Bremen gGmbH, D-28759 Bremen, Germany

^c Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstrasse 30, D-48149 Münster, Germany

Abstract

Reactions of tin(IV) complexes of the type Sn(PyS)₂X₂ (X = Cl, PyS, Ph; PyS = pyridine-2-thiolate) with Pd(PPh₃)₄ provide easy access to novel heterometallic complexes with Pd–Sn bonds. Electronic characteristics of this connection were analysed by X-ray crystallography, ¹¹⁹Sn Mössbauer spectroscopy and quantum chemical analyses.

This article is part of the themed collection: 2014 Emerging Investigators

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C3CC47912A
Article type: Communication
Submitted: 16 Oki 2013
Accepted: 02 Des 2013
First published: 03 Des 2013

Download Citation

Chem. Commun., 2014,50, 5382-5384

Permissions

Request permissions

Pyridine-2-thiolate bridged tin–palladium complexes with Sn(PdN₂Cl₂), Sn(PdN₂S₂), Sn(PdN₂C₂) and Sn(Pd₂N₄) skeletons

E. Wächtler, R. Gericke, L. Zhechkov, T. Heine, T. Langer, B. Gerke, R. Pöttgen and J. Wagler, Chem. Commun., 2014, 50, 5382 DOI: 10.1039/C3CC47912A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications