Issue 40, 2014

Pyridine-2-thiolate bridged tin–palladium complexes with Sn(PdN2Cl2), Sn(PdN2S2), Sn(PdN2C2) and Sn(Pd2N4) skeletons

Abstract

Reactions of tin(IV) complexes of the type Sn(PyS)2X2 (X = Cl, PyS, Ph; PyS = pyridine-2-thiolate) with Pd(PPh3)4 provide easy access to novel heterometallic complexes with Pd–Sn bonds. Electronic characteristics of this connection were analysed by X-ray crystallography, 119Sn Mössbauer spectroscopy and quantum chemical analyses.

Graphical abstract: Pyridine-2-thiolate bridged tin–palladium complexes with Sn(PdN2Cl2), Sn(PdN2S2), Sn(PdN2C2) and Sn(Pd2N4) skeletons

Supplementary files

Article information

Article type
Communication
Submitted
16 Oki 2013
Accepted
02 Des 2013
First published
03 Des 2013

Chem. Commun., 2014,50, 5382-5384

Pyridine-2-thiolate bridged tin–palladium complexes with Sn(PdN2Cl2), Sn(PdN2S2), Sn(PdN2C2) and Sn(Pd2N4) skeletons

E. Wächtler, R. Gericke, L. Zhechkov, T. Heine, T. Langer, B. Gerke, R. Pöttgen and J. Wagler, Chem. Commun., 2014, 50, 5382 DOI: 10.1039/C3CC47912A

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