Issue 40, 2014

Group 3 metal stilbene complexes: synthesis, reactivity, and electronic structure studies

Abstract

Group 3 metal (E)-stilbene complexes supported by a ferrocene diamide ligand were synthesized and characterized. Reactivity studies showed that they behave similar to analogous naphthalene complexes. Experimental and computational results indicated that the double bond was reduced and not a phenyl ring, in contrast to a previously reported uranium (E)-stilbene complex.

Graphical abstract: Group 3 metal stilbene complexes: synthesis, reactivity, and electronic structure studies

Supplementary files

Article information

Article type
Communication
Submitted
01 Oki 2013
Accepted
15 Nov 2013
First published
18 Nov 2013

Chem. Commun., 2014,50, 5221-5223

Group 3 metal stilbene complexes: synthesis, reactivity, and electronic structure studies

W. Huang, P. M. Abukhalil, S. I. Khan and P. L. Diaconescu, Chem. Commun., 2014, 50, 5221 DOI: 10.1039/C3CC47505K

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