Negative area compressibility in silver(I) tricyanomethanide

Sarah A. Hodgson; Jasper Adamson; Sarah J. Hunt; Matthew J. Cliffe; Andrew B. Cairns; Amber L. Thompson; Matthew G. Tucker; Nicholas P. Funnell; Andrew L. Goodwin

doi:10.1039/C3CC47032F

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Negative area compressibility in silver(i) tricyanomethanide†

Sarah A. Hodgson,^a Jasper Adamson,^a Sarah J. Hunt,^a Matthew J. Cliffe,^a Andrew B. Cairns,^a Amber L. Thompson,^a Matthew G. Tucker,^bc Nicholas P. Funnell^a and Andrew L. Goodwin*^a

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^a Department of Chemistry, University of Oxford, Inorganic Chemistry Laboratory, South Parks Road, Oxford OX1 3QR, UK
E-mail: andrew.goodwin@chem.ox.ac.uk
Fax: +44 (0)1865 274690
Tel: +44 (0)1865 272137

^b ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, UK

^c Diamond Light Source, Harwell Campus, Didcot, UK

Abstract

The molecular framework Ag(tcm) (tcm⁻ = tricyanomethanide) expands continuously in two orthogonal directions under hydrostatic compression. The first of its kind, this negative area compressibility behaviour arises from the flattening of honeycomb-like layers during rapid pressure-driven collapse of the interlayer separation.

This article is part of the themed collection: 2014 Emerging Investigators

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DOI: https://doi.org/10.1039/C3CC47032F
Article type: Communication
Submitted: 13 Seb 2013
Accepted: 09 Des 2013
First published: 09 Des 2013
This article is Open Access

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Chem. Commun., 2014,50, 5264-5266

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Negative area compressibility in silver(I) tricyanomethanide

S. A. Hodgson, J. Adamson, S. J. Hunt, M. J. Cliffe, A. B. Cairns, A. L. Thompson, M. G. Tucker, N. P. Funnell and A. L. Goodwin, Chem. Commun., 2014, 50, 5264 DOI: 10.1039/C3CC47032F

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Chemical Communications

Negative area compressibility in silver(i) tricyanomethanide†

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Negative area compressibility in silver(I) tricyanomethanide

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