The pattern of incorporation of [4-2H, 4-13C] mevalonic acid and H218O into dihydrobotrydial has confirmed that there is a 1, 3-hydride shift in the biosynthesis of this metabolite and that there is a discharge of the C(9) carbocation by hydration.
A. P. W. Bradshaw, J. R. Hanson and I. H. Sadler, J. Chem. Soc., Chem. Commun., 1981, 1169 DOI: 10.1039/C39810001169
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