Issue 34, 2020
From the journal:

Organic & Biomolecular Chemistry

Boracene-based alkylborate enabled Ni/Ir hybrid catalysis†

Yukiya Sato,a   Yusuke Miyamoto,a   Yuto Sumida, ORCID logo *a   Takamitsu Hosoya ORCID logo bc  and  Hirohisa Ohmiya ORCID logo *ad  

* Corresponding authors

a Division of Pharmaceutical Sciences, Graduate School of Medical Sciences, Kanazawa University, Kanazawa 920-1192, Japan
E-mail: sumida@p.kanazawa-u.ac.jp, ohmiya@p.kanazawa-u.ac.jp

b Laboratory for Chemical Biology, RIKEN Center for Biosystems Dynamics Research (BDR), Kobe 650- 0047, Japan

c Laboratory of Chemical Bioscience, Institute of Biomaterials and Bioengineering, Tokyo Medical and Dental University (TMDU), Tokyo 101-0062, Japan

d JST, PRESTO, 4-1-8 Honcho, Kawaguchi, Saitama, Japan

Abstract

Boracene-based alkylborate enabled visible light-mediated metallaphotoredox catalysis. The directly excited borate was easily oxidatively quenched by an excited Ir photoredox catalyst. Ni/Ir hybrid catalysis afforded the products under significantly low irradiance.

Graphical abstract: Boracene-based alkylborate enabled Ni/Ir hybrid catalysis

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D0OB01610A
Article type
Communication
Submitted
05 Agu 2020
Accepted
11 Agu 2020
First published
11 Agu 2020

Org. Biomol. Chem., 2020,18, 6598-6601

Author version available


Download author version (PDF)

Permissions

Request permissions

Boracene-based alkylborate enabled Ni/Ir hybrid catalysis

Y. Sato, Y. Miyamoto, Y. Sumida, T. Hosoya and H. Ohmiya, Org. Biomol. Chem., 2020, 18, 6598 DOI: 10.1039/D0OB01610A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements