Issue 92, 2018

Ca(ii), Yb(ii) and Tm(iii) complexes with tri- and tetra-anions of 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene

Abstract

Reduction of [(dpp-bian)2−M2+(thf)4] (M = Ca, 1; Yb, 6; dpp-bian = 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) by alkali metals results in heterometallic, [(dpp-bian)3−M2+K+(thf)2]2 (M = Ca, 2; Yb, 7), [(dpp-bian)4−Ca2+A2+(thf)4]2 (A = Na, 3; Li, 4; K, 5), [(dpp-bian)4−Yb2+K2+(thf)4]2 (8) and [(dpp-bian)24−Yb32+K2+(thf)8] (9). The reduction of [(dpp-bian)TmBr(thf)n] (in situ) affords [(dpp-bian)4−Tm3+Na+(thf)]2 (10).

Graphical abstract: Ca(ii), Yb(ii) and Tm(iii) complexes with tri- and tetra-anions of 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene

Supplementary files

Article information

Article type
Communication
Submitted
13 Okt 2018
Accepted
22 Okt 2018
First published
01 Nov 2018

Chem. Commun., 2018,54, 12950-12953

Ca(II), Yb(II) and Tm(III) complexes with tri- and tetra-anions of 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene

I. L. Fedushkin, D. A. Lukina, A. A. Skatova, A. N. Lukoyanov and A. V. Cherkasov, Chem. Commun., 2018, 54, 12950 DOI: 10.1039/C8CC08108E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements