Issue 5, 2021

A self-assembled tetrathiafulvalene box

Abstract

A M8L2 metalla-cage constructed through coordination-driven self-assembly from a quinonato bis-ruthenium complex and an electron-rich tetrathiafulvalene (TTF) tetrapyridyl ligand is depicted. In this molecular box, both TTF units are highly bent and are separated by a distance as short as 3.48 Å in the solid state. This system offers a unique opportunity to study the electronic interactions occurring between two TTF units facing each other in a conformationally rigid environment.

Graphical abstract: A self-assembled tetrathiafulvalene box

Supplementary files

Article information

Article type
Research Article
Submitted
08 Dez 2020
Accepted
07 Jan 2021
First published
08 Jan 2021

Org. Chem. Front., 2021,8, 883-890

A self-assembled tetrathiafulvalene box

S. Krykun, V. Croué, O. Alévêque, E. Levillain, M. Allain, C. Mézière, V. Carré, F. Aubriet, Z. Voïtenko, S. Goeb and M. Sallé, Org. Chem. Front., 2021, 8, 883 DOI: 10.1039/D0QO01543A

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