Issue 23, 2020

The same oxygenation-state introduction of hypervalent sulfur under transition-metal-free conditions

Abstract

Sulfonyl compounds have attracted considerable interest due to their extensive applications in drug discovery. Access to the assembly of SO2-containing compounds via the oxygenation oxidative-state introduction of hypervalent sulfur has come to the fore in recent years. This review discusses the application of the same oxygenation-state introduction of hypervalent sulfur strategy under transition-metal-free conditions, and presents it in light of different atoms being linked to the sulfonyl group, including sulfones, sulfonamides, sulfonyl fluorides and thiosulfonates.

Graphical abstract: The same oxygenation-state introduction of hypervalent sulfur under transition-metal-free conditions

Article information

Article type
Review Article
Submitted
17 Aug 2020
Accepted
16 Okt 2020
First published
16 Okt 2020

Org. Chem. Front., 2020,7, 3956-3966

The same oxygenation-state introduction of hypervalent sulfur under transition-metal-free conditions

D. Zeng, M. Wang, W. Deng and X. Jiang, Org. Chem. Front., 2020, 7, 3956 DOI: 10.1039/D0QO00987C

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