Issue 6, 2018

Photoinduced hydroxylperfluoroalkylation of styrenes

Abstract

A transition metal- and organophotocatalyst-free hydroxylperfluoroalkylation of styrenes under visible-light irradiation was developed. In this protocol, an electron donor–acceptor complex (perfluoroalkyl iodide and tertiary amine) was employed for the introduction of a perfluorinated chain and molecular oxygen was used as a green oxidant for the generation of hydroxyl groups. Various styrenes successfully undergo the reaction affording the corresponding fluorine-containing alcohols in up to 96% yields.

Graphical abstract: Photoinduced hydroxylperfluoroalkylation of styrenes

Supplementary files

Article information

Article type
Research Article
Submitted
18 Okt 2017
Accepted
04 Jan 2018
First published
08 Jan 2018

Org. Chem. Front., 2018,5, 1045-1048

Photoinduced hydroxylperfluoroalkylation of styrenes

T. Chen, Y. Guo, K. Sun, L. Wu, W. Liu, C. Liu, Y. Huang and Q. Chen, Org. Chem. Front., 2018, 5, 1045 DOI: 10.1039/C7QO00946A

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