Issue 1, 2017

Ru/ceria-catalyzed direct formylation of amines and CO to produce formamides

Abstract

We herein report a new strategy of directly converting amines and CO to formamides with 100% atom utilization efficiency. It is suitable for up to 25 amine substrates with no additives. Ru/ceria is found to be an excellent catalyst for this reaction due the efficient co-activation of CO and amine on Ru species.

Graphical abstract: Ru/ceria-catalyzed direct formylation of amines and CO to produce formamides

Supplementary files

Article information

Article type
Communication
Submitted
17 Sep 2016
Accepted
13 Okt 2016
First published
14 Okt 2016

Green Chem., 2017,19, 88-92

Ru/ceria-catalyzed direct formylation of amines and CO to produce formamides

Y. Wang, J. Zhang, H. Chen, Z. Zhang, C. Zhang, M. Li and F. Wang, Green Chem., 2017, 19, 88 DOI: 10.1039/C6GC02603F

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