Issue 90, 2021

[2.2]Paracyclophane-bridged platinum(ii) complexes for silver(i) recognition with emission enhancement

Abstract

A [2.2]paracyclophane-bridged bimetallic alkynylplatinum(II) terpyridyl complex displays severe emission quenching due to the presence of intramolecular π–π interactions. It undergoes an adaptive conformational change upon recognizing Ag+, which attenuates the intramolecular stacking strength and thereby exhibits “turn-on” emission character.

Graphical abstract: [2.2]Paracyclophane-bridged platinum(ii) complexes for silver(i) recognition with emission enhancement

Supplementary files

Article information

Article type
Communication
Submitted
28 Aug 2021
Accepted
15 Okt 2021
First published
16 Okt 2021

Chem. Commun., 2021,57, 11996-11999

[2.2]Paracyclophane-bridged platinum(II) complexes for silver(I) recognition with emission enhancement

Y. Tian, B. Chen, S. Jiang, M. Yuan, J. Ren and F. Wang, Chem. Commun., 2021, 57, 11996 DOI: 10.1039/D1CC04806F

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