Recent progress in CO2 conversion into organic chemicals by molecular catalysis

Qing-Wen Song, Ran Ma, Ping Liu, Kan Zhang and Liang-Nian He

Green Chem., 2023, 25, 6538
DOI: 10.1039/D3GC01892J

CO2 fixation: cycloaddition of CO2 to epoxides using practical metal-free recyclable catalysts

Wuttichai Natongchai, Daniel Crespy and Valerio D’Elia

Chem. Commun., 2025, 61, 419
DOI: 10.1039/D4CC05291A

Fluorine-decorated ionic liquid salts used for the efficient transformation of low concentration CO2

Haitao Su, Jingxu Han, Can Fang, Tonghao Dai, Zhouxian Wang, Zhifeng Dai, Huagang Ni, Yubing Xiong and Xiangju Meng

New J. Chem., 2025, 49, 6615
DOI: 10.1039/D5NJ00615E

Evaluating metal-free quaternized boronate esters as efficient catalysts for the fixation of CO2 with epoxides to form cyclic carbonates under suitable conditions

Eyyup Yasar, Emine Aytar and Ahmet Kilic

React. Chem. Eng., 2024, 9, 2938
DOI: 10.1039/D4RE00282B

Green innovations in C–H bond functionalisation: exploring homogeneous recyclable catalytic systems

Dewal S. Deshmukh, Sanjay Singh, Kirtikumar C. Badgujar, Vivek T. Humne, Gajanan V. Korpe and Bhalchandra M. Bhanage

Green Chem., 2025, 27, 5667
DOI: 10.1039/D5GC00278H

A mechanistic study on coupling of CO2 and epoxide mediated by guanidine/TBAI catalysts

Yihua Fu, Yan Zhang, Changwei Hu and Zhishan Su

New J. Chem., 2024, 48, 920
DOI: 10.1039/D3NJ04395A

Systematic investigation of the role of the epoxides as substrates for CO2 capture in the cycloaddition reaction catalysed by ascorbic acid

Thalía Ortiz-García, Sergio Posada-Pérez, Layla El-Khchin, David Dalmau, Juan V. Alegre-Requena, Miquel Solà, Valerio D'Elia and Albert Poater

Ind. Chem. Mater., 2025, 3, 452
DOI: 10.1039/D5IM00037H

Rational design of graphdiyne-based single-atom catalysts for electrochemical CO2 reduction reaction

Liyun Jiang, Mengdie Zhao and Qi Yu

RSC Adv., 2024, 14, 27365
DOI: 10.1039/D4RA04643A

Novel Hybrid Gel–Fiber Membranes as Carriers for Lipase Catalysis Based on Electrospinning and Gelation Technology

Shumiao Lin, Qianqian Zhang, Ziheng Wang and Jinlong Li

Gels, 2024, 10, 74
DOI: 10.3390/gels10010074

Functional ionic liquids based on DABCO: Efficient catalysts for chemical fixation of CO 2 into cyclic carbonates

Xiaoli Jia, Yindi Fan, Tong Chen, Yuxin Li, Yueyu Zhang and Sanhu Zhao

Synthetic Communications, 2024, 54, 1450
DOI: 10.1080/00397911.2024.2394089

Synthesis of cyclic carbonates from CO2 and epoxides by novel metal and halide-free chiral boron compounds

Ahmet Kilic, Valerio D’Elia, Emine Aytar, Chalida Phungpanya and Fatma Aslanli

Tetrahedron, 2025, 174, 134485
DOI: 10.1016/j.tet.2025.134485

Carbon Sphere Anchored Hydroxylamino-Decorated Ionic Liquids for CO2 Fixation into Cyclic Carbonates at Mild Conditions

Yanhui Kang, Xiaopeng Li, Jinwei Zhang, Shenjun Qin, Yongjing Hao, Balaji Panchal, Tao Chang and Zheng Zhu

Catal Lett, 2024, 154, 1611
DOI: 10.1007/s10562-023-04443-7

CO2 Valorization in Deep Eutectic Solvents

Zhenbo Guo, Zhicheng Zhang, Yuchen Huang, Tianxing Lin, Yixin Guo, Liang‐Nian He and Tianfei Liu

ChemSusChem, 2024
DOI: 10.1002/cssc.202400197

Efficient Selective Catalytic Fixation of CO2 into Epoxide to Form Cyclic Carbonates Using Sodium Aluminate Engineered Gamma Alumina Catalyst

Rajanna Dhanusha, Puneethkumar M. Srinivasappa, Sarat Chandra Alla, Manjunath Hemavathi, Divya Prasad, Nitin K. Chaudhari and Arvind H. Jadhav

Applied Organom Chemis, 2024, 38
DOI: 10.1002/aoc.7429

Optimization and kinetics modeling of CO2 fixation into cyclic carbonates using urea-functionalized ionic organic polymers under mild conditions

Qirui Yin, Xinhui Li, Xiuli Yan, Xiangjie Zhang, Shenjun Qin, Yongjing Hao, Ningning Li, Zheng Zhu, Xiaohuan Liu and Tao Chang

Molecular Catalysis, 2023, 550, 113601
DOI: 10.1016/j.mcat.2023.113601

Experimental and kinetic evaluation on cobalt Salen conjugated organic polymers for CO2 cycloaddition reactions and iodine vapor adsorption

Tingchun Zhu, Shuangshuo Li, Meiqi Sun, Ningning Li, Xuanbo Liu, Yuhang Zhang, Tao Chang, Yongjing Hao and Zheng Zhu

Journal of Molecular Liquids, 2024, 401, 124651
DOI: 10.1016/j.molliq.2024.124651

Promotion mechanism of hydroxyl groups in catalyzing CO2 cycloaddition

Yiming Wang, Wensheng Wei, Yuxin Wang, Guangwen Xu, Jinggang Zhao and Lei Shi

Journal of CO2 Utilization, 2025, 91, 102999
DOI: 10.1016/j.jcou.2024.102999

Samarium- and Ytterbium-Grafted Periodic Mesoporous Silica for Carbon Dioxide Capture and Conversion

Jitpisut Poolwong, Felix Kracht, Eric Moinet, Yucang Liang, Valerio D’Elia and Reiner Anwander

Inorg. Chem., 2023, 62, 17972
DOI: 10.1021/acs.inorgchem.3c02995

Light-Driven CO2 Fixation into Epoxides Using an Al2O3/CoAl2O4 Composite Photocatalyst

Khushboo S. Paliwal, Deepanjan Patra, Avishek Roy, Antarip Mitra, Biplop Jyoti Hazarika and Venkataramanan Mahalingam

Inorg. Chem., 2025, 64, 1808
DOI: 10.1021/acs.inorgchem.4c04375

Polyhydroxyurethanes from Biobased Monomers and CO2: A Bridge between Sustainable Chemistry and CO2 Utilization†

Tharinee Theerathanagorn, Tanika Kessaratikoon, Hafeez Ur Rehman, Valerio D'Elia and Daniel Crespy

Chin. J. Chem., 2024, 42, 652
DOI: 10.1002/cjoc.202300531

Effects of Mixed Metal Oxide Catalysts on the Synthesis of Cyclic Carbonates from Epoxides under Atmospheric CO2 Pressure

Blanca Ivonne Vergara-Arenas, Rachel L. Nicholls, Guillermo E. Negrón-Silva, Leticia Lomas-Romero, José Antonio Morales-Sern and Bao N. Nguyen

ACS Omega, 2025, 10, 673
DOI: 10.1021/acsomega.4c07538

Visible‐Light‐Driven Cycloaddition of CO2 with Epoxides Catalyzed by Recyclable Mg2⁺/TiO2 Photocatalyst Operating at Room Temperature

Md. Saddam Hossain, Mayu Yuasa, Yohei Kametani, Yoshihito Shiota, Yu Hoshino, Keita Shichijo, Mamoru Fujitsuka and Hisashi Shimakoshi

Chemistry A European J, 2025
DOI: 10.1002/chem.202501845

Cycloaddition of CO2 to epoxides catalyzed by homogeneous metalorganic complexes under ambient conditions: an update

Suthida Kaewsai and Valerio D’ Elia

Journal of Organometallic Chemistry, 2025, 1039, 123799
DOI: 10.1016/j.jorganchem.2025.123799

Dissociation role on the catalytic activity of organic halides in CO2 conversion to cyclic carbonates: Experimental and computational study

Elisa Hernández, Pablo Navarro, Paolo P. Pescarmona and José Palomar

Journal of CO2 Utilization, 2024, 88, 102929
DOI: 10.1016/j.jcou.2024.102929

Synthesis of Bifunctional Catalysts for the Cycloaddition of CO2 to Epoxides through an Epoxide‐Driven Strategy

Suthida Kaewsai, Silvano Del Gobbo and Valerio D'Elia

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202301713

Highly efficient synthesis of cyclic carbonates via deep eutectic solvents from CO2 at the gas-liquid interface of microdroplet under atmospheric pressure condition

Leizhi Zheng, Xiemin Liu, Guoqiang Yang, Jia Liu, Bowen Jiang, Ying Liu, Xinyao Li, Xingbang Hu and Zhibing Zhang

Chemical Engineering Science, 2024, 289, 119867
DOI: 10.1016/j.ces.2024.119867

Epoxide/CO2 Cycloaddition Reaction Catalyzed by Indium Chloride Complexes Supported by Constrained Inden Schiff‐Base Ligands

Thitirat Piyawongsiri, Nattiya Laiwattanapaisarn, Arnut Virachotikul, Phongnarin Chumsaeng and Khamphee Phomphrai

ChemPlusChem, 2023, 88
DOI: 10.1002/cplu.202300559

Aniline-Based Hyper-Cross-Linked Polymer–In2O3 Composite Boosting CO2 Epoxide Ring-Opening Reaction Activity without Cocatalysts

Kunpeng Song, Tao Wang, Sini He, Yunwen Liao and Bin Xu

ACS Appl. Polym. Mater., 2024, 6, 4739
DOI: 10.1021/acsapm.4c00297

Propylene carbonate synthesis routes using CO2: DFT and thermodynamic analysis

Anag Katiyar, Pankaj Kumar, Vimal Chandra Srivastava and Vimal Kumar

Journal of Molecular Structure, 2025, 1321, 139935
DOI: 10.1016/j.molstruc.2024.139935

Design and synthesis of a multifunctional g-C3N4@MOF for enhanced CO2 cycloaddition: Synergistic effects of Lewis acid-base sites and ionic liquid functionalization

Guofeng Zhao, Peng Qin, Chao Zhang, Chao Wang, Delu Zhang, Tao Zhuang and Zhiguo Lv

Journal of Organometallic Chemistry, 2025, 1026, 123494
DOI: 10.1016/j.jorganchem.2024.123494

Applications and Synthesis of Chiral Cyclic Carbonates from Asymmetric CO2 Conversion

Banyong Suwankaisorn, Suthida Kaewsai, Wuttichai Natongchai and Valerio D’ Elia

Asian J Org Chem, 2025, 14
DOI: 10.1002/ajoc.202500320

High‐Performance and Recyclable Multisite Catalytic System for CO2 Fixation Using Crown Ether‐Linked Schiff Base and Alkali Halides

Md. Saddam Hossain, Yu Hoshino and Hisashi Shimakoshi

Adv Synth Catal, 2025, 367
DOI: 10.1002/adsc.202500246

Hydroxy-Rich Covalent Organic Framework for the Efficient Catalysis of the Cycloaddition of CO2

Yiying Pang, Bowei Wang, Xiaoyi Gu, Huawei Shen, Xilong Yan, Yang Li and Ligong Chen

Langmuir, 2023, 39, 16721
DOI: 10.1021/acs.langmuir.3c01719

Catalytic Strategies for the Cycloaddition of CO2 to Epoxides in Aqueous Media to Enhance the Activity and Recyclability of Molecular Organocatalysts

Niracha Tangyen, Wuttichai Natongchai and Valerio D’Elia

Molecules, 2024, 29, 2307
DOI: 10.3390/molecules29102307