Analysis of reduced paramagnetic shifts as an effective tool in NMR spectroscopy

Alexander A. Pavlov, Valentin V. Novikov, Igor A. Nikovskiy, Elizaveta K. Melnikova, Yulia V. Nelyubina and Dmitry Y. Aleshin

Phys. Chem. Chem. Phys., 2022, 24, 1167
DOI: 10.1039/D1CP04648A

Synthesis, X-ray structure and magnetic properties of the apically functionalized monocapped cobalt(ii) tris-pyridineoximates possessing SMM behaviour

Alexander S. Belov, Svetlana A. Belova, Nikolay N. Efimov, Veronika V. Zlobina, Valentin V. Novikov, Yulya V. Nelyubina, Yan V. Zubavichus, Yan Z. Voloshin and Alexander A. Pavlov

Dalton Trans., 2023, 52, 2928
DOI: 10.1039/D2DT04073E

Delving into theoretical and computational considerations for accurate calculation of chemical shifts in paramagnetic transition metal systems using quantum chemical methods

Md. Ashraful Islam and Andrew J. Pell

Phys. Chem. Chem. Phys., 2024, 26, 12786
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A High‐Resolution View of the Coordination Environment in a Paramagnetic Metalloprotein from its Magnetic Properties

Enrico Ravera, Lucia Gigli, Elizaveta A. Suturina, Vito Calderone, Marco Fragai, Giacomo Parigi and Claudio Luchinat

Angew Chem Int Ed, 2021, 60, 14960
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Spin State Behavior of A Spin-Crossover Iron(II) Complex with N,N′-Disubstituted 2,6-bis(pyrazol-3-yl)pyridine: A Combined Study by X-ray Diffraction and NMR Spectroscopy

Elizaveta Melnikova, Dmitry Aleshin, Igor Nikovskiy, Gleb Denisov and Yulia Nelyubina

Crystals, 2020, 10, 793
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Electronic structure of mononuclear and radical-bridged dinuclear cobalt(II) single-molecule magnets

David Hunger, Julia Netz, Simon Suhr, Komalavalli Thirunavukkuarasu, Hans Engelkamp, Björn Fåk, Uta Albold, Julia Beerhues, Wolfgang Frey, Ingo Hartenbach, Michael Schulze, Wolfgang Wernsdorfer, Biprajit Sarkar, Andreas Köhn and Joris van Slageren

Nat Commun, 2025, 16
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Purely Spectroscopic Determination of the Spin Hamiltonian Parameters in High-Spin Six-Coordinated Cobalt(II) Complexes with Large Zero-Field Splitting

Eugenii Ya. Misochko, Alexander V. Akimov, Denis V. Korchagin, Joscha Nehrkorn, Mykhaylo Ozerov, Andrew V. Palii, Juan Modesto Clemente-Juan and Sergey M. Aldoshin

Inorg. Chem., 2019, 58, 16434
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Spin-Crossover in Iron(II) Complexes of N,N′-Disubstituted 2,6-Bis(Pyrazol-3-yl)Pyridines: An Effect of a Distal Substituent in the 2,6-Dibromophenyl Group

Igor A. Nikovskiy, Alexander V. Polezhaev, Valentin V. Novikov, Dmitry Yu. Aleshin, Rinat R. Aysin, Elizaveta K. Melnikova, Luca M. Carrella, Eva Rentschler and Yulia V. Nelyubina

Crystals, 2021, 11, 922
DOI: 10.3390/cryst11080922

Observability of Paramagnetic NMR Signals at over 10 000 ppm Chemical Shifts

Jonas C. Ott, Elizaveta A. Suturina, Ilya Kuprov, Joscha Nehrkorn, Alexander Schnegg, Markus Enders and Lutz H. Gade

Angewandte Chemie, 2021, 133, 23038
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Coordination [CoII2] and [CoIIZnII] Helicates Showing Slow Magnetic Relaxation

Rosa Diego, Alexander Pavlov, Mohanad Darawsheh, Dmitry Aleshin, Joscha Nehrkorn, Yulia Nelyubina, Olivier Roubeau, Valentin Novikov and Guillem Aromí

Inorg. Chem., 2019, 58, 9562
DOI: 10.1021/acs.inorgchem.9b01334

Solvent-Induced Encapsulation of Cobalt(II) Ion by a Boron-Capped tris-Pyrazoloximate

Alexander S. Belov, Yan Z. Voloshin, Alexander A. Pavlov, Yulia V. Nelyubina, Svetlana A. Belova, Yan V. Zubavichus, Varvara V. Avdeeva, Nikolay N. Efimov, Elena A. Malinina, Konstantin Yu. Zhizhin and Nikolay T. Kuznetsov

Inorg. Chem., 2020, 59, 5845
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Multifrequency Nuclear Magnetic Resonance as an Efficient Tool To Investigate Heterospin Complexes in Solutions

Natalya N. Fishman, Nikita N. Lukzen, Konstantin L. Ivanov, Mariya V. Edeleva, Sergey V. Fokin, Galina V. Romanenko and Victor I. Ovcharenko

J. Phys. Chem. A, 2020, 124, 1343
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Inductive detection of temperature-induced magnetization dynamics of molecular spin systems

Anatoly R. Melnikov, Mikhail Yu. Ivanov, Arkady A. Samsonenko, Yaroslav V. Getmanov, Igor A. Nikovskiy, Anna K. Matiukhina, Ekaterina N. Zorina-Tikhonova, Julia K. Voronina, Alexander S. Goloveshkin, Konstantin A. Babeshkin, Nikolay N. Efimov, Mikhail A. Kiskin, Igor L. Eremenko, Matvey V. Fedin and Sergey L. Veber

The Journal of Chemical Physics, 2024, 160
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A High‐Resolution View of the Coordination Environment in a Paramagnetic Metalloprotein from its Magnetic Properties

Enrico Ravera, Lucia Gigli, Elizaveta A. Suturina, Vito Calderone, Marco Fragai, Giacomo Parigi and Claudio Luchinat

Angewandte Chemie, 2021, 133, 15087
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Influence of Polymorphism on the Magnetic Properties of Single-Molecule Magnets According to the Data of EPR Spectroscopy in the Terahertz Range

V. V. Novikov, A. A. Pavlov, J. Nehrkorn and Yu. V. Nelyubina

Russ J Coord Chem, 2020, 46, 756
DOI: 10.1134/S1070328420110056

Theoretical Basis for Switching a Kramers Single Molecular Magnet by Circularly-Polarized Radiation

Alexander G. Maryasov, Michael K. Bowman, Matvey V. Fedin and Sergey L. Veber

Materials, 2019, 12, 3865
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Slow Magnetic Relaxation in {[CoCxAPy)] 2.15 H2O}n MOF Built from Ladder-Structured 2D Layers with Dimeric SMM Rungs

Ana Arauzo, Elena Bartolomé, Javier Luzón, Pablo Alonso, Angelica Vlad, Maria Cazacu, Mirela Zaltariov, Sergiu Shova, Juan Bartolomé and Constantin Turta

Molecules, 2021, 26, 5626
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New Spin‐Crossover Complexes of Substituted 2,6‐Bis(pyrazol‐3‐yl)pyridines

Alexander A. Pavlov, Dmitry Yu. Aleshin, Igor A. Nikovskiy, Alexander V. Polezhaev, Nikolay N. Efimov, Alexander A. Korlyukov, Valentin V. Novikov and Yulia V. Nelyubina

Eur J Inorg Chem, 2019, 2019, 2819
DOI: 10.1002/ejic.201900432

A Quantum Chemistry View on Two Archetypical Paramagnetic Pentacoordinate Nickel(II) Complexes Offers a Fresh Look on Their NMR Spectra

Enrico Ravera, Lucia Gigli, Barbara Czarniecki, Lucas Lang, Rainer Kümmerle, Giacomo Parigi, Mario Piccioli, Frank Neese and Claudio Luchinat

Inorg. Chem., 2021, 60, 2068
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A Synergy and Struggle of EPR, Magnetometry and NMR: A Case Study of Magnetic Interaction Parameters in a Six-Coordinate Cobalt(II) Complex

Alexander A. Pavlov, Joscha Nehrkorn, Sergey V. Zubkevich, Matvey V. Fedin, Karsten Holldack, Alexander Schnegg and Valentin V. Novikov

Inorg. Chem., 2020, 59, 10746
DOI: 10.1021/acs.inorgchem.0c01191

Paramagnetic Pyrazolylborate Complexes Tp2M and Tp*2M: 1H, 13C, 11B, and 14N NMR Spectra and First-Principles Studies of Chemical Shifts

Ari Pyykkönen, Robert Feher, Frank H. Köhler and Juha Vaara

Inorg. Chem., 2020, 59, 9294
DOI: 10.1021/acs.inorgchem.0c01176

Cobalt(II) “Scorpionate” complexes as electronic ground state models for cobalt-substituted zinc enzymes: Structure investigation by magnetic circular dichroism

Nicholas M. Plugis, Nathan D. Rudd, J. Krzystek, Dale C. Swenson, Joshua Telser and James A. Larrabee

Journal of Inorganic Biochemistry, 2020, 203, 110876
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In Situ NMR Search for Spin-Crossover in Heteroleptic Cobalt(II) Complexes

Yanina Pankratova, Dmitry Aleshin, Igor Nikovskiy, Valentin Novikov and Yulia Nelyubina

Inorg. Chem., 2020, 59, 7700
DOI: 10.1021/acs.inorgchem.0c00716

NMR for Single Ion Magnets

Lucia Gigli, Silvia Di Grande, Enrico Ravera, Giacomo Parigi and Claudio Luchinat

Magnetochemistry, 2021, 7, 96
DOI: 10.3390/magnetochemistry7070096

Room-Temperature Spin Crossover in a Solution of Iron(II) Complexes with N,N′-Disubstituted Bis(pyrazol-3-yl)pyridines

Dmitry Yu Aleshin, Igor Nikovskiy, Valentin V. Novikov, Alexander V. Polezhaev, Elizaveta K. Melnikova and Yulia V. Nelyubina

ACS Omega, 2021, 6, 33111
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Modern physical methods for the molecular design of single-molecule magnets

Valentin V. Novikov and Yulia V. Nelyubina

Russ. Chem. Rev., 2021, 90, 1330
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A New Single-Molecule Magnet Based on a Cage Cobalt(II) Complex

D. Yu. Aleshin, A. A. Pavlov, S. A. Belova, N. N. Efimov, A. S. Belov, V. V. Novikov and Ya. Z. Voloshin

Russ. J. Inorg. Chem., 2019, 64, 1532
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Selective Pathway toward Heteroleptic Spin-Crossover Iron(II) Complexes with Pyridine-Based N-Donor Ligands

Igor Nikovskiy, Dmitry Yu. Aleshin, Valentin V. Novikov, Alexander V. Polezhaev, Ekaterina A. Khakina, Elizaveta K. Melnikova and Yulia V. Nelyubina

Inorg. Chem., 2022, 61, 20866
DOI: 10.1021/acs.inorgchem.2c03270

Towards the Molecular Design of Spin‐Crossover Complexes of 2,6‐Bis(pyrazol‐3‐yl)pyridines

Igor Nikovskiy, Alexander Polezhaev, Valentin Novikov, Dmitry Aleshin, Alexander Pavlov, Elnara Saffiulina, Rinat Aysin, Pavel Dorovatovskii, Lydia Nodaraki, Floriana Tuna and Yulia Nelyubina

Chemistry A European J, 2020, 26, 5629
DOI: 10.1002/chem.202000047

Synthesis, structural, spectroscopic and magnetic studies of tetranuclear Ni(II) and Co(II) clusters based on cyclobutyl and cyclopentyl-substituted analogues of zoledronic acid

Tomasz Rojek, Katarzyna Ślepokura, Vasyl Kinzhybalo, Marek Duczmal, Agnieszka Wojciechowska and Ewa Matczak-Jon

Polyhedron, 2023, 233, 116301
DOI: 10.1016/j.poly.2023.116301

Unexpected Side Products of Chemical Transformations in Cobalt(II) Pseudoclathrochelates: An X‐Ray Diffraction Study

Yu. V. Nelyubina, A. S. Belov, S. A. Belova, Y. V. Zubavichus, S. Malinkin and Y. Z. Voloshin

ChemistrySelect, 2020, 5, 12307
DOI: 10.1002/slct.202001876

High-Spin Cobalt(II) Complex with Record-Breaking Anisotropy of the Magnetic Susceptibility According to Paramagnetic NMR Spectroscopy Data

Ya. A. Pankratova, Yu. V. Nelyubina, V. V. Novikov and A. A. Pavlov

Russ J Coord Chem, 2021, 47, 10
DOI: 10.1134/S1070328420120052

Observability of Paramagnetic NMR Signals at over 10 000 ppm Chemical Shifts

Jonas C. Ott, Elizaveta A. Suturina, Ilya Kuprov, Joscha Nehrkorn, Alexander Schnegg, Markus Enders and Lutz H. Gade

Angew Chem Int Ed, 2021, 60, 22856
DOI: 10.1002/anie.202107944