Issue 25, 2010
From the journal:

Chemical Communications

Unusual magnetic properties of a two-coordinate heteroleptic linear cobalt(ii) complex†

Chengbao Ni,a   Troy A. Stich,a   Gary J. Longb  and  Philip P. Power*a  

* Corresponding authors

a Department of Chemistry, University of California, One Shields Avenue, Davis, USA
E-mail: pppower@ucdavis.edu
Fax: +1 530-752-8995
Tel: +1 530-752-6910

b Department of Chemistry, Missouri University of Science and Technology, University of Missouri, Rolla, Missouri 65409-0010, USA

Abstract

The synthesis and characterization of two-coordinate cobalt(II) complexes CoAr′2 (1) and Ar′CoN(SiMe3)2 (2) (Ar′ = C6H3-2,6-(C6H3-2,6-iPr2)2) are reported. The magnetic data for 2 show that it has an unexpectedly high μeff of 5.65 μB whereas the bent complex 1 has a significantly lower moment.

Graphical abstract: Unusual magnetic properties of a two-coordinate heteroleptic linear cobalt(ii) complex

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C001483D
Article type
Communication
Submitted
22 Ian 2010
Accepted
15 Apr 2010
First published
20 Mai 2010

Chem. Commun., 2010,46, 4466-4468

Permissions

Request permissions

Unusual magnetic properties of a two-coordinate heteroleptic linear cobalt(II) complex

C. Ni, T. A. Stich, G. J. Long and P. P. Power, Chem. Commun., 2010, 46, 4466 DOI: 10.1039/C001483D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements