Issue 57, 2014

On-surface Ullmann polymerization via intermediate organometallic networks on Ag(111)

Abstract

The role of organometallic intermediates during on-surface polymerization via Ullmann coupling was studied on Ag(111). The polymerization progress was monitored by X-ray photoelectron spectroscopy (XPS). Scanning Tunneling Microscopy (STM) was used to characterize organometallic and covalent networks and to identify the temperature regimes for organometallic and covalent bond formation.

Graphical abstract: On-surface Ullmann polymerization via intermediate organometallic networks on Ag(111)

Supplementary files

Article information

Article type
Communication
Submitted
14 Apr 2014
Accepted
19 Mai 2014
First published
21 Mai 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 7680-7682

Author version available

On-surface Ullmann polymerization via intermediate organometallic networks on Ag(111)

J. Eichhorn, T. Strunskus, A. Rastgoo-Lahrood, D. Samanta, M. Schmittel and M. Lackinger, Chem. Commun., 2014, 50, 7680 DOI: 10.1039/C4CC02757D

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