Issue 2, 2012

Porphyrin based porous organic polymers: novel synthetic strategy and exceptionally high CO2adsorption capacity

Abstract

Iron containing porous organic polymers (Fe-POPs) have been synthesized by a facile one-pot bottom-up approach to porphyrin chemistry by an extended aromatic substitution reaction between pyrrole and aromatic dialdehydes in the presence of small amount of Fe(III). The Fe-POPs possess very high BET surface area, large micropores and showed excellent CO2 capture (∼19 wt%) at 273 K/1 bar.

Graphical abstract: Porphyrin based porous organic polymers: novel synthetic strategy and exceptionally high CO2 adsorption capacity

Supplementary files

Article information

Article type
Communication
Submitted
15 Quint 2011
Accepted
24 Oct 2011
First published
16 Nov 2011

Chem. Commun., 2012,48, 248-250

Porphyrin based porous organic polymers: novel synthetic strategy and exceptionally high CO2 adsorption capacity

A. Modak, M. Nandi, J. Mondal and A. Bhaumik, Chem. Commun., 2012, 48, 248 DOI: 10.1039/C1CC14275E

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