Different reactivity of the heavier group 14 element alkyne analogues Ar′MMAr′ (M = Ge, Sn; Ar′ = C6H3-2,6(C6H3-2,6-Pri2)2) with R2NO

Geoffrey H. Spikes; Yang Peng; James C. Fettinger; Jochen Steiner; Philip P. Power

doi:10.1039/B513189H

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Different reactivity of the heavier group 14 elementalkyne analogues Ar′MMAr′ (M = Ge, Sn; Ar′ = C₆H₃-2,6(C₆H₃-2,6-Prⁱ₂)₂) with R₂NO†

Geoffrey H. Spikes,^a Yang Peng,^a James C. Fettinger,^a Jochen Steiner^a and Philip P. Power*^a

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^a Department of Chemistry, University of California Davis, One Shields Ave., Davis, CA 95616, USA
E-mail: pppower@ucdavis.edu
Fax: 001 530 752 8995
Tel: 001 530 752 6913

Abstract

The reactions of the digermanium and ditin alkyne analogues Ar′MMAr′ (M = Ge or Sn) with R₂NO, (R₂NO = Me₂C [upper bond 1 start] (CH₂)₃CMe₂N [upper bond 1 end] O or N₂O), result in complete MM bond cleavage to afford the germylene :Ge(Ar′)ONR₂ or the germanium(II) or tin(II) hydroxides {M(Ar′)(μ–OH)}₂.

This article is part of the themed collection: Philip Power at 65: an icon of organometallic chemistry

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Article information

DOI: https://doi.org/10.1039/B513189H
Article type: Communication
Submitted: 16 Sept 2005
Accepted: 06 Oct 2005
First published: 09 Nov 2005

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Chem. Commun., 2005, 6041-6043

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Different reactivity of the heavier group 14 element alkyne analogues Ar′MMAr′ (M = Ge, Sn; Ar′ = C₆H₃-2,6(C₆H₃-2,6-Prⁱ₂)₂) with R₂NO

G. H. Spikes, Y. Peng, J. C. Fettinger, J. Steiner and P. P. Power, Chem. Commun., 2005, 6041 DOI: 10.1039/B513189H

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