Issue 20, 2000

Persistent phosphinyl radicals from a bulky diphosphine: an example of a molecular jack-in-the-boxElectronic supplementary information (ESI) available: summary of GED details and theoretical results. See http://www.rsc.org/suppdata/cc/b0/b004889p/

Abstract

The structure of the phosphinyl radical, ṖR2 [R = CH(SiMe3)2], has been determined by gas-phase electron diffraction (GED) together with ab initio molecular orbital calculations, and that of the corresponding diphosphine, (PR2)2, has been established by X-ray crystallography; the diphosphine behaves as an energy storage reservoir.

Supplementary files

Article information

Article type
Communication
Submitted
08 Iun 2000
Accepted
22 Sext 2000
First published
02 Oct 2000

Chem. Commun., 2000, 2045-2046

Persistent phosphinyl radicals from a bulky diphosphine: an example of a molecular jack-in-the-box

S. L. Hinchley, C. A. Morrison, D. W. H. Rankin, C. L. B. Macdonald, R. J. Wiacek, A. H. Cowley, M. F. Lappert, G. Gundersen, J. A. C. Clyburne and P. P. Power, Chem. Commun., 2000, 2045 DOI: 10.1039/B004889P

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