Issue 7, 2025

Visible-light-promoted azidation/arylation of unactivated alkenes with Togni-N3via electron donor–acceptor complexes

Abstract

A visible-light-promoted azidation/arylation of unactivated alkenes with Togni-N3 has been achieved, leading to a series of azidated pyrrolo[1,2-a]indoles under photocatalyst-free conditions. Notably, an EDA complex derived from the electron-rich indole derivatives and Togni-N3 served as the key intermediate in this reaction.

Graphical abstract: Visible-light-promoted azidation/arylation of unactivated alkenes with Togni-N3via electron donor–acceptor complexes

Supplementary files

Article information

Article type
Communication
Submitted
18 Nov 2024
Accepted
30 Dec 2024
First published
30 Dec 2024

Org. Biomol. Chem., 2025,23, 1607-1611

Visible-light-promoted azidation/arylation of unactivated alkenes with Togni-N3via electron donor–acceptor complexes

P. Xie, Y. Gao, C. Wu, P. Cheng, Y. Zhang and S. Sun, Org. Biomol. Chem., 2025, 23, 1607 DOI: 10.1039/D4OB01861C

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